SELECT 
  * 
FROM 
  cscart_product_options_exceptions 
WHERE 
  product_id = 622 
ORDER BY 
  exception_id

Query time 0.00029

Explain
id select_type table type possible_keys key key_len ref rows Extra
1 SIMPLE cscart_product_options_exceptions ref product product 3 const 2 Using where; Using filesort

Result

exception_id product_id combination
1986 622 a:2:{i:760;s:5:"16351";i:761;s:5:"16358";}
1987 622 a:2:{i:760;s:5:"16351";i:761;s:5:"16359";}